The new discrete aluminum alkoxide complex ( i PrO)Al{CH 2 NMeCH 2 C(CF 3 ) 2 O} 2 ( 1 ) initiates the controlled ring-opening polymerization of caprolactone in dichloromethane at 20 °C with high activity (TOF = 250 h - 1 ) and productivity (TON up to 1000), leading to polymers with high molecular weight and narrow molecular weight distribution.
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Amgoune et al. (2005) studied this question.
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