Über Reaktionen des 2,4,6‐Tris(trifluormethyl)phenols mit Verbindungen von Hauptgruppen‐ und Nebengruppen‐Elementen (Li, Na, Mg, Ca, Ba, Ge, Sn und Ti, W, Mn, Cd)

Reactions of 2,4,6‐Tris(trifluoromethyl)phenols with Compounds of Main Group (Li, Na, Mg, Ca. Ba, Ge. Sn) and Transition (Ti, W, Mn, Cd) Elements The 2,4,6‐tris(trifluoromethyl)phenoxides of composition RfONa · 1.5 THF (2), [Rf = 2,4,6‐(CF3)3C6H2], RfOLi · 0.75 Et2O (3), (RfO)2Mg · 3 THF (4), (RfO)2Ca · 3 THF (5), (RfO)2Ba · THF (6), (RfO)2 (7), (RfO)2Me2NWWNMe2(ORf)2 (8), (RfO)2Ge · THF (9), (RfO)2Sn · THF (10), (η5‐C5Me5)TiCl2ORf (11), (RfO)2Mn · 3 THF (12), and (RfO)2 · 2 THF (13) are prepared. The singlecrystal X‐ray structures of 4, 8, and 12 are described.