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The transition of the near-infrared (NIR) region from singlet to triplet excited states (S–T transition) is effective to ensure wideband photosensitization. Here, we synthesize iminopyridine Ru(II) complexes, exhibiting S–T transitions in the NIR region. The dye-sensitized solar cell using the imino-pyridine Ru(II) complex exhibits photoelectric conversion by employing the aforementioned S–T transition. The transition of the near-infrared (NIR) region from singlet to triplet excited states (S–T transition) is effective to ensure wideband photosensitization. Here, we synthesize the iminopyridine Ru(II) complexes, which exhibit S–T transitions in the NIR region. A dye-sensitized solar cell using the iminopyridine Ru(II) complex exhibits photoelectric conversion by employing the aforementioned S–T transition.
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Kinoshita et al. (2018) studied this question.
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