Relativistic corrections to the fine structure of the hydrogen atom have been calculated by many authors, but the experimental confirmation of the theory, or alternatively the determination of the numerical value of the fine-structure constant α, is limited to an accuracy of 110⁵ because of the short lifetime of 2²P states of hydrogen. However, in view of the fact that 2³P states of helium have a longer lifetime, we expect that the fine-structure intervals of the 2³P states of helium can be measured to an accuracy of 110⁶ or better. With this expectation, we attempted to evaluate semirelativistically the theoretical formula for the helium fine structure to the order α⁴ Ry.
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Kee Yong Kim (1965) studied this question.
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