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An environmentally friendly one-pot reaction for conjugate radical additions to activated olefins, with good to excellent yields, uses organoboranes generated in situ as radical precursors and the Barton carbonate PTOC-OMe as a radical-chain transfer reagent [Eq. (1)]. PTOC=pyridine-2-thione-N-oxycarbonyl.
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Ollivier et al. (2000) studied this question.
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