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We describe the synthesis and structures of the first tantalum-containing nitride-chlorides, Ba(3)Ta(3)N(6)Cl and Ba(15)Ta(15)N(33)Cl(4), and the structurally related Ba(3)Si(3)N(5)OCl, and their relationship with a theoretical silaceous framework.
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Barnes et al. (2007) studied this question.
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