Sulfated Temperature Effects on the Catalytic Activity of CeO2 in NH3-Selective Catalytic Reduction Conditions

In this work, the influence of sulfated temperature on the selective catalytic reduction of NO by NH 3 over the sulfated CeO 2 was investigated. The NO conversion of the sulfated CeO 2 samples decreased with the increase of sulfated temperature. The fresh CeO 2 and the CeO 2 sulfated at different temperatures were characterized by X-ray diffraction (XRD), laser Raman spectroscopy (LRS), in situ diffuse reflectance infrared Fourier transform spectroscopy (in situ DRIFTS), thermogravimetry and differential thermal analysis (TG-DTA), H 2 -temperature-programmed reduction (H 2 -TPR), and X-ray photoelectron spectroscopy (XPS). The obtained results indicate that the sulfation process was gradually deepened, and the existence states of sulfate species over CeO 2 were changed from surface sulfates to bulk-like sulfates and to bulk sulfates with raising the sulfated temperature. Meanwhile, the formed bulk-like and bulk sulfates were the main reason to result in the decrease of catalytic activity. In addition, the corresponding model was proposed to understand the interaction between sulfate species and CeO 2 influenced by sulfated temperature. Finally, bulk sulfates could be eliminated by H 2 O washing and the NO conversion of CeO 2 sulfated at 550 °C was recovered after H 2 O washing, which supports the proposed model.