High Resolution Image Download MS PowerPoint Slide A photocatalyst-free and mild visible light photochemical procedure for C(sp 3 )–H arylation of amides is described. The reaction proceeds via an electron donor–acceptor (EDA) complex between an electron-rich arene substrate and electron-poor persulfate oxidant. C(sp 3 )–H arylation of the amide occurs selectively with the most electron-rich arene of the substrate. Mechanistic studies corroborate the reaction taking place in a solvent cage holding components in a close proximity.
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Kaur et al. (2021) studied this question.
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