Thermodynamic versus kinetic control: Small-angle neutron scattering (SANS) and single-crystal X-ray diffraction data have been used to elucidate the effect of temperature, solvent, and metal identity on the formation of dimeric or hexameric metal-seamed pyrogallol[4]arene capsules. Higher temperatures, methanol solution, and the use of nickel metal favor dimer formation (see scheme).
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Kumari et al. (2012) studied this question.
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