High activity and selectivity is exhibited by the FePd cluster 1 on SiO2 in the reductive carbonylation of o-nitrophenol to benzoxazol-2-one. A conventional catalyst prepared from iron oxalate and palladium acetate is far less effective. The catalyst prepared from 1 retains its activity even after repeated use.
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Braunstein et al. (1985) studied this question.
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