Discovery of Far-Infrared Pure Rotational Transitions of CH[TSUP]+[/TSUP] in NGC 7027

We report the discovery of the rotational spectrum of CH + in the Infrared Space Observatory Long Wavelength Spectrometer (LWS) spectrum of the planetary nebula NGC 7027. The identification relies on a 1996 reanalysis of the LWS spectrum by Liu et al. and on new LWS data. The strong line at 179.62 μm (coinciding with the 2 12 -1 01 transition of water vapor) and the lines at 119.90 and 90.03 μm (reported as unidentified by Liu et al.), whose frequencies are in the harmonic relation 2 : 3:4, are shown to arise from the J = 2-1, 3-2, and 4-3 rotational transitions of CH + . This identification is strengthened by the new LWS spectra of NGC 7027, which clearly show the next two rotational lines of CH + at 72.140 and 60.247 μm. This is the first time that the pure rotational spectrum of CH + has been observed. This discovery opens the possibility of probing the densest and warmest zones of photodissociation regions. We derive a rotational temperature for the CH + lines of 150 ± 20 K and a CH + /CO abundance ratio of 2-6 × 10 -4 .