Domain constrained: Polar and nonpolar domains within 1-alkyl-3-methylimidazolium ionic liquids can affect reaction outcomes by pseudo-encapsulation of reactants and this has been explored for a nucleophilic substitution reaction using a cationic substrate and a range of nucleophiles. The significant rate enhancements observed correlate with the concentration of the polar reactants within the ionic liquid's polar domain. ([CnMIM]=1-alkyl-3-methylimidazolium).
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Weber et al. (2012) studied this question.
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