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The published data on the synthesis of organomagnesium compounds assisted by metal complex catalysts are generalised and described systematically for the first time. Hydro-, carbo- and cyclomagnesiation reactions of unsaturated compounds with R 1 MgR 2 (R 1 = Alk, Ar; R 2 = H, Hal; R 1 = R 2 = Alk) catalysed by Ti, Zr and other transition metal salts and complexes are considered. Selected examples of applications of organomagnesium reagents to organic synthesis are given.
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Джемилев et al. (2005) studied this question.
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