Seven cyclopentadienyl–NHC piano‐stool iron complexes were prepared and studied in the catalytic hydrosilylation of aldehydes and ketones under visible light irradiation. A significant acceleration of the rate was observed when the reactions were carried out under solvent‐free conditions. Single‐crystal X‐ray structural analyses were performed for complexes 5 and 7.
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Bézier et al. (2011) studied this question.
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