Fabrication and Characterization of Er/Yb Co-Doped Fluorophosphosilicate Glass Core Optical Fibers

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The technical process of the synthesis of a fluorophosphosilicate (FPS) glass core was thoroughly investigated for the first time utilizing a modified chemical vapor deposition (MCVD) all-gas-phase fabrication method. It was discovered that the limiting doping level of the silica glass simultaneously co-doped with phosphorus (P) and fluorine (F) was found to be confined by the formation of POF3 gas. The dopants content was achieved as high as 4.7 at% of P and 1.1 at% of F in a glass core, respectively. A developed “in-house” manufacturing method makes it possible to fabricate a large mode area (LMA) purely single-mode Er–Yb co-doped optical fibers with a core diameter of 20 μm and with a lasing efficiency comparable to commercially available LMA Er–Yb optical fibers.