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January 1, 2012ElectrochemistryOpen Access

Electrochemical Behavior of Magnesium in Mixed Solutions Consisting of Ionic Liquid and Alkylmagnesiumbromides with Different Alkyl-Chains

Nobuko Yoshimoto Keisuke Hotta Makoto Egashira Masayuki Morita

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Abstract

Electrochemical deposition and dissolution of magnesium have been investigated in organic solutions consisting of alkylmagnesiumbromides/tetrahydrofuran (RMgBr/THF) having different alkyl-chains mixed with an ionic liquid. Coulombic efficiency for cathodic deposition and anodic dissolution of magnesium, obtained from voltammetric responses, decreased with the increase in the alkyl-chain length of the magnesium complex. The highest current response was observed in the electrolyte system consisting of CH3MgBr/THF with a quaternary ammonium salt-based ionic liquid.

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Yoshimoto et al. (2012) studied this question.

synapsesocial.com/papers/6aad105a69aef9ab1ed21ac1 https://doi.org/10.5796/electrochemistry.80.774

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