Theoretical review demonstrates modern approximations for the Schrödinger equation in multielectron atoms, highlighting principles of orbital distribution and atomic terms.
This article describes modern approaches to the description of the electronic structure of multielectron atoms. The problem of solving the Schrödinger equation for systems containing two or more electrons is discussed. Approaches to the approximate solution of the Schrödinger equation and the features of electron distribution among atomic orbitals in multielectron atoms are considered. The concept of an atomic term and methods for its determination are also discussed.
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A. N. Gusev (2026) studied this question.
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