Sintering Mechanisms of Zirconium and Hafnium Carbides Doped with MoSi 2

The microstructure of two pressureless‐sintered ultra‐high‐temperature ceramics, namely ZrC+20 vol% MoSi 2 and HfC+20 vol% MoSi 2 , was characterized by scanning and transmission electron microscopy. With regard to the ZrC–MoSi 2 system, Zr x Si y compounds and SiC were detected. In the HfC–MoSi 2 system, a mixed phase was detected at the triple points and identified as (Mo,Hf) 5 Si 3 . For both the systems investigated, the high wettability of the silicide‐based phases on the matrix grains suggests that sintering is assisted by a liquid phase. This contribution reports for the first time on the sintering mechanisms of early transition metal carbides doped with MoSi 2 as a sinter additive, on the basis of the microstructural evolution observed upon sintering and in the light of phase diagrams and thermodynamical calculations.