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March 28, 2008Organometallics

Bending of “Uranocene” ((η8-C8H8)2U): Synthesis and Crystal Structure of the Cyanido Complex [(η8-C8H8)2U(CN)][NEt4]

J.‐C. Berthet P. Thuéry M. Ephritikhine

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Abstract

The two parallel, eight-membered rings of uranocene were forced to bend upon addition of CN − to give the title compound.

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Berthet et al. (2008) studied this question.

synapsesocial.com/papers/6aadd8aaacef0af25695a600 https://doi.org/10.1021/om800006u

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Bis(cyclooctatetraenyl)uranium (uranocene). A new class of sandwich complexes that utilize atomic f orbitalsOriginal Research · 1968 · 370 citations
2Preparation and properties of uranocene, di-.pi.-cyclooctatetraeneuranium(IV)Original Research · 1973 · 108 citations
3Uranocene. The First Member of a New Class of Organometallic Derivatives of the f ElementsOriginal Research · 2004 · 122 citations
4Covalency in bis([8]annulene)uranium from photoelectron spectroscopy with variable photon energyOriginal Research · 1989 · 65 citations
5Covalency in f-Element Organometallic Complexes: Theory and ExperimentReview · 1989 · 88 citations

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The Oxidation State of Ce in the Sandwich Molecule Cerocene1996
Lanthanide(III) complexes with cyclooctatetraene dianion. Synthetic chemistry, characterization, and physical properties1973

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