Chemical transport experiments are a valuable aid of great potential in the synthesis and thermochemical characterization of solids. Compounds of interest can often only be crystallized by this method. The use of a transport balance allows very detailed observations, particularly of the course of the experiment over time (simultaneous or sequential deposition of multiple-phase solids). The computer program CVTRANS enables a quantitative thermochemical description of the experiment based on the cooperative transport model. A compilation of recent results illustrates the development and efficiency of the method. The transport of phosphides, anhydrous phosphates and sulfates, and rare-earth oxide and oxohalide compounds are treated in detail.
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Gruehn et al. (2000) studied this question.
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