A thiourea-functionalized benzo-15-crown-5 (TU-B15C5), adsorbed at the 1,2-dichloroethane–water interface, can bind H2PO4− selectively over hydrophobic anions (H2PO4− > Cl−, ClO4−, Br−, CH3COO−) via the formation of hydrogen bonds.
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Shigemori et al. (2002) studied this question.
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