Polarization reversal by intramolecular disordering in organic ferroelectrics: trichloroacetamide

Mechanism of successive ferroelectric–paraelectric phase transitions exhibited by an organic ferroelectric, trichloroacetamide, is clarified through structural and calorimetric experiments. The transition mechanism, intramolecular disordering, reasonably explains the polarization reversal. This mechanism is only possible in molecular solids and is applicable to other compounds as a possible strategy to design new molecular ferroelectrics. Also revealed is the incommensurate nature of the intermediate phase, the origin of which is briefly discussed at phenomenological and molecular levels.