Reaction of copper(I) chloride with 2,2‐bis(diphenylphosphinomethyl)‐l‐phenylthiopropane P2S produced a dimeric species [(P2S)CuC1]2 (2). Treatment of 2 with silver nitrate in acetonitrile gave a hexameric crystalline metal complex {[(P2S)Cu(CH3CN)]6+6NO3} (4), which had a “cyclodextrin‐type” structure. A linear polymeric copper complex [(P2S)Cu(NO3)]n was obtained by recrystallization of 4 in chloroform. These complexes were characterized by single crystal analyses, and their coordination behaviors in solution are discussed.
No takes yet. Share an insight, caveat, or question.
Wang et al. (1991) studied this question.
Synapse has enriched one closely related paper. Consider it for comparative context: