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Green synthesis of a 3D, Mn( ii ) MOF, [Mn 3 (NDC) 3 (DMA) 4 ] n ( 1 ) has been achieved by employing mechanochemical and sonochemical routes and 1′ exhibits an interesting gas uptake properties with a high value of isosteric heat of adsorption ( Q st ) for H 2 .
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Dhankhar et al. (2016) studied this question.
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