Organopalladium polymers of buckminsterfullerene, C60Pdn, catalyze hydrogenation of olefins and acetylenes at room temperature under a hydrogen atmosphere. The catalytic activity is mainly dependent on the ratio of C60 to Pd in the polymers. Partial hydrogenation of acetylenes is achieved by adding benzylamine as the cocatalyst.
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Nagashima et al. (1992) studied this question.
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