• Magnetic chitosan nanoparticles grafted with diethyleneamine were synthesized. • U(VI) sorption from sulfuric acid solutions is exothermic and spontaneous. • Langmuir equation fits sorption isotherms. • Uptake kinetics is modeled by the pseudo-second order rate equation. • U(VI) is efficiently desorbed with acidic urea solutions; sorbent can be recycled. Magnetic nano-based particles of diethylenetriamine-functionalized chitosan have been synthesized before being characterized by elemental analysis, FT-IR spectroscopy, XRD, AFM, TEM and VSM analysis. Uranium adsorption (from synthetic solutions) has been investigated in batch systems. The effects of different experimental parameters such as initial solution pH (controlled with sulfuric acid), equilibration time, initial uranium concentration and temperature on sorption performance have been determined. The nano-based particles, with size in the range 10–30 nm, are super-paramagnetic. The kinetic data can be efficiently modelled using the pseudo-second-order equation. The Langmuir and the Dubinin–Radushkevich (D–R) equations fit well sorption isotherms. The value of activation energy ( E DR = 8.39 kJ/mol) indicates that the process is associated to chemical interactions (rather than pure physical sorption). In addition the values of thermodynamic parameters (Δ G ° and Δ H °) show that the process is spontaneous and exothermic. The positive value of Δ S ° means that the randomness of the system increased with sorption. Finally, the adsorbent can be efficiently regenerated and recycled for at least 5 cycles using acidified urea as the eluent.
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Mahfouz et al. (2014) studied this question.
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