The new charge-transfer salt β‘ ‘-(BEDT-TTF)4[(H3O)Cr(C2O4)3]S, where BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene and S = CH2Cl2, has a broad metal−insulator transition at approximately 150 K. This differs from similar salts in the BEDT-TTF tris(oxalato) metalate series, notably the superconducting materials with S = PhCN and the salt with S = C5H5N, which has a sharp metal−insulator transition.
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Rashid et al. (2001) studied this question.
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