(Di- tert -butylphosphanyl- P -ethyl)cyclopentadienylcobalt(I) complexes 1 and 2 were treated with 3,3-disubstituted cyclopropenes to give isoprene and vinylcarbene complexes. The diphenylvinylcarbene complex reacted with tert -butylphosphaethyne to give unusual coupling products.
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Foerstner et al. (1998) studied this question.
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