The hydrazido(2-) complexes [MoX2(NNH2)(PMe2Ph)3] (X=Cl or Br) derived from bis(dinitrogen) complex and HX react with aldehydes or ketones to give a series of diazoalkane complexes [MoX2(←=N–N=CRR′)(PMe2Ph)3].
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Mizobe et al. (1980) studied this question.
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