A mixed-valence {Mn(32)} complex, containing Mn(II), Mn(III) and Mn(IV) ions, with a probable S = 5 ground state, utilizes pivalate as a capping ligand and a variety of oxo-type bridging ligands. AC susceptibility data on fresh samples suggest that the Mn(32) complex is one of the largest nuclearity single molecule magnets found to date.
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Langley et al. (2011) studied this question.
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