Oxygen A-band absorption spectra exhibit interference between O2 monomer (with a discrete line at 762 nm) and O2 dimol (which also exhibits a band spectrum at 762 nm) absorption. Analysis of the absorbance spectrum between 750 nm and 770 nm reveals P, Q, and R branches, characteristic of rovibrational transitions. Pure oxygen spectra were analyzed at pressures ranging from 1 to 25 bar and at temperatures of 298 K, 323 K, 348 K, and 373 K using advanced data analysis methods. Integrated absorbance, Gaussian and Lorentzian full width at half maximum height (FWHM), and maximum absorbance peak positions were calculated for the R and P branches, and relevant formulas were deduced.
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Muhammad A. AL-Jalali (2025) studied this question.
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