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January 23, 2004Journal of the American Chemical Society

Isolation of a Stable 1-Iridabicyclo[3.2.0]hepta-1,3,6-triene and Its Reversible Transformation into an Iridacycloheptatriene

Margarita Paneque Manuel L. Poveda Nuria Rendón K. Mereiter

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Abstract

Reaction of the iridacyclopentadiene complex 2 with 2-butyne yields a mixture in equilibrium of the iridacycloheptatriene 3 and a novel 1-iridabicyclo[3.2.0]hepta-1,3,6-triene, 4.

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Paneque et al. (2004) studied this question.

synapsesocial.com/papers/6aaf261ac3c4a1ab74f16620 https://doi.org/10.1021/ja0393527

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