A Chemically Functionalized Carboxylate−Alumoxane Nanoparticle Support for Olefin Polymerization Catalysts

A metallocene/MAO-based solid olefin polymerization catalyst has been developed using chemically functionalized nanoparticles (carboxylate−alumoxanes) as a well-defined substrate. Reaction of p -hydroxybenzoate−alumoxane ( p -HB-A) nanoparticles, formed from the acid with boehmite, with methylalumoxane (MAO) results in a solid nanoparticle-based MAO (n-MAO), which in combination with zirconocenes [including Cp 2 ZrCl 2, Cp 2 ZrMe 2, and ( n BuCp) 2 ZrCl 2 ] produces an active solid catalyst for olefin polymerization. The catalytic activity of the n-MAO-based catalyst is comparable to the homogeneous analogue and a traditional silica-supported catalyst under identical reaction conditions and with the same Al (MAO):Zr ratio. The n-MAO approach offers the potential of the MAO being easily chemically modified.