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The reactive nitridomolybdenum(VI) fragment 1 is available from the reaction of [CpMo2Cl6] with azides. Aggregation occurs in different ways depending on the conditions to afford compounds containing six-membered rings with either localized or delocalized metal–nitrogen multiple bonds. The nature and structure of the products indicates that 1 has a nucleophilic nitrido ligand.
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Herrmann et al. (1995) studied this question.
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