Evaluation of the Arrhenius behavior of n -dodecane radical cation (RH˙ + ) reactivity with lanthanide ion-complexed N , N , N ′, N ′-tetraoctyl diglycolamide (TODGA)

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, respectively. The similar and relatively large barrier energy suggests a common reaction mechanism involving electron abstraction from one of the coordinating nitrate anions, which is consistent with previously reported decreased degradation of TODGA complexes under radiolytic environments.