The resonance Raman spectra of specifically deuteriated divalent d6 metal complexes are reported. These include the iron(II) and ruthenium(II) perdeuteriated complexes and the Ru(bpy‐3,3′‐d2)32+ and Ru(bpy‐6,6′‐d2)32+ complex ions. The syntheses of the deuteriated ligands are reported and the frequency shifts observed on deuteriation are correlated with the natural abundance iron(II), ruthenium(II) and osmium(II) complexes.
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McClanahan et al. (1984) studied this question.
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