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The kinetics of initial steps of formation of polyetherols in the reaction between melamine and ethylene carbonate in dimethylsulfoxide in presence of 1,4‐diazabicyclo[2.2.2]octane (DABCO) as catalyst was studied. Based upon kinetic studies performed with various concentrations of melamine and catalyst, the rate law was formulated and a mechanism of the reaction was proposed. The activation parameters ΔG#, ΔH#, and ΔS# were obtained from the temperature dependence of kinetics.
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Kijowska et al. (2004) studied this question.
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