Inorganic–organic hybrid mesoporous material incorporating organoruthenium complexes within its organosilica frameworks (HMM–phRuCpPF6) has been successfully prepared by a ligand exchange reaction. HMM–phRuCpPF6 acts as a unique heterogeneous catalyst for hydrosilylation of 1-hexyne to produce α-vinylsilane at elevated temperatures.
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Kamegawa et al. (2011) studied this question.
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