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In a follow‐up study of the cobalt(II) member 1 of a family of isostructural cubane clusters of type [C(NH2)3]8[MII4(cit)4]·8H2O (cit = citrate, M = Mg, Mn, Fe, Co, Ni, Zn) by measuring AC magnetic susceptibilities, as a function of frequency, this compound clearly displays behaviour typical of magnetization reversal and slow magnetic relaxation (ΔE = 13.1 K, τo = 8.4 × 10–7 s). A related octanuclear cluster [Co8(C4O7)4(H2O)12]·24H2O (2) that contains a [Co4(C4O7)4] cubane moiety, behaves likewise (ΔE = 20.5 K, τo = 1.0 × 10–7 s).(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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Moubaraki et al. (2008) studied this question.
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