January 1, 1988Journal of the Chemical Society Chemical Communications

The reversible protonation of rhenium( VII ) heptahydrides of type [ReH 7 (PR 3 ) 2 ] to give η 2 -dihydrogen complexes

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Abstract

The first examples of the protonation of d0 metal complexes of type [ReH7(PR3)2][PR3= P(cyclohexyl)3, PPh3 or PBut2Me], to give η2-H2 complexes, are described.

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Fontaine et al. (1988) studied this question.

synapsesocial.com/papers/6aaf8958e8b0ac81b6a5f9ea https://doi.org/10.1039/c39880000482

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Abstract

The first examples of the protonation of d0 metal complexes of type [ReH7(PR3)2][PR3= P(cyclohexyl)3, PPh3 or PBut2Me], to give η2-H2 complexes, are described.