Dichloro‐ and dihydridoruthenium(II) catalysts attached to an amphiphilic resin (PS−PEG) were prepared and tested for hydrogenation of supercritical carbon dioxide (scCO2) in the presence of dimethylamine leading to N,N‐dimethylformamide (DMF). The supported catalysts were successfully recyclable with only moderate loss of activity.
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Kayaki et al. (2003) studied this question.
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