The changes in the electronic transitions of three coordination compounds in various solvents are analyzed with the Unified Solvation model. The examples selected illustrate the influence of specific and non-specific solvation on the spectral shift. The Unified Solvation approach provides a quantitative way of determining whether the coordination complex is behaving as a donor, acceptor, or amphoterically in various solvents. The Unified solvation approach provides a quantitative procedure for evaluating the role of solvent, and this understanding allows one to optimize solvent selection for the multitude of physicochemical studies of coordination compounds.
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Drago et al. (1994) studied this question.
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