March 1, 1989Inorganic ChemistryOpen Access

Electrophilic cleavage of carbon-fluorine bonds in hydrido trifluoromethyl complexes of platinum(II) by proton acids. Synthesis of hydrido carbene and hydrido carbonyl derivatives and x-ray structures of trans-PtH(CF3)(PPh3)2 (180 K) and trans-[PtH[cyclic](COCH2CH2O)(PPh3)2]BF4 (298 K)

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Abstract

Synthesis of Hydrido Carbene and Hydrido Carbonyl Derivatives and low temperature X-ray Structures of trans-PtH(CF3)(PPh3)2 (180 K) and trans-[PtH(COCH2CH2O)(PPh3)2]BF4 (298 K) has been determined.

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Cite This Study

Michelin et al. (1989) studied this question.

synapsesocial.com/papers/6aaf9c73292bb98df525e726 https://doi.org/10.1021/ic00304a009

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Abstract

Synthesis of Hydrido Carbene and Hydrido Carbonyl Derivatives and low temperature X-ray Structures of trans-PtH(CF3)(PPh3)2 (180 K) and trans-[PtH(COCH2CH2O)(PPh3)2]BF4 (298 K) has been determined.