An adaptation of the David and Gosselain formula for redox catalyzed telomerization was made. An equation was developed for transfer reactions between oligomer radicals and metallic ions. This equation was applied to data obtained in chlorotrifluoroethylene (CTFE)—carbon tetrachloride telomerizations catalyzed by a ferric chloride—benzoin mixture. It was found that the metal ion transfer constants (CMei) were the predominant parameters influencing the distribution of products obtained. These were found constant for degrees of polymerization greater than 2.
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Boutevin et al. (1981) studied this question.
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