Thermodynamic information for copper compounds and aqueous species, including estimated values at elevated temperatures, is analyzed. Potential-pH diagrams (Pourbaix diagrams) for the CuH2O, FeH2O, and FeCuH2O systems are presented, and the solubilities of copper and iron oxides (including mixed copperiron oxide) are evaluated. These results are used to interpret the observed precipitation of oxides on boiling water reactor (BWR) fuel and to estimate the effect of hydrogen water chemistry on their behavior.
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Daniel Cubicciotti (1988) studied this question.
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