The oxidation of n-decane in a high-pressure jet-stirred reactor (JSR) has been investigated experimentally in a wide range of conditions covering the low and high temperature oxidation regimes (550-1150K, lOatm, Ø = 0.1 to 1.5), Reactants, intermediates and final products have been measured providing a detailed picture of n-decane oxidation. Cyclic ethers resulting from the so-called Iwo-temperature oxidation chemistry of n-decane were identified. The results are interpreted in terms of reaction mechanism. A detailed chemical kinetic modeling of the high-temperature oxidation of n-decane is used to assess the influence of low temperature chemistry in the intermediate temperature range.
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Dagaut et al. (1994) studied this question.
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