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January 1, 2008Chemical Communications

Regioselective 12CO/13CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the Hox state of [FeFe]-hydrogenase

Christine M. Thomas Tianbiao Liu Michael B. Hall Marcetta Y. Darensbourg

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Abstract

A mixed-valent Fe(ii)Fe(i) model of the H(ox) state of [FeFe]-hydrogenase is shown, under certain conditions, to exhibit regioselective (12)CO/(13)CO exchange activity similar to that observed for H(ox).

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Thomas et al. (2008) studied this question.

synapsesocial.com/papers/6ab0999b421a6686c714ed6e https://doi.org/10.1039/b719559a

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