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June 1, 1995Bulletin of the Chemical Society of Japan

Structure and Magnetic Properties of a Nitroxide Diruthenium(II,III) Complex, [Ru2(O2CCMe3)4(tempo)2][Ru2(O2CCMe3)4(H2O)2](BF4)2 (tempo = 2,2,6,6-Tetramethylpiperidine-1-oxyl)

Makoto Handa Yasuyoshi Sayama Masahiro Mikuriya R. Nukada Ichiro Hiromitsu Kuninobu Kasuga

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Abstract

A nitroxide complex, [Ru2(O2CCMe3)4(tempo)2][Ru2(O2CCMe3)4(H2O)2](BF4)2 (tempo = 2,2,6,6-tetramethylpiperidine-1-oxyl) has been prepared and characterized by elemental analysis, X-ray crystal structure analysis, and variable temperature magnetic susceptibility and ESR spectrum measurements. A fairly large antiferromagnetic interaction (J = −130 cm−1) between the diruthenium core and the nitroxide radical has been observed.

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Cite This Study

Handa et al. (1995) studied this question.

synapsesocial.com/papers/6ab0acb353e47274bbe79023 https://doi.org/10.1246/bcsj.68.1647

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