Metal-free carbon-based hybrids composed of reduced graphene oxide (rGO) and C 3 N 3 S 3 polymers with a layered “sandwich” structure were fabricated by an in situ two-step polymerization strategy and used as visible light photocatalysts for selective aerobic oxygenation of benzylic alcohols to the corresponding aldehydes, at good efficiency and high selectivity. This work shows the great potential and prospective application of the metal-free C 3 N 3 S 3 polymer in the photocatalyzed synthesis of fine chemicals.
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Xu et al. (2014) studied this question.
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