Widely tunable difference frequency generation source for high-precision mid-infrared spectroscopy

We have developed a widely tunable mid-infrared difference frequency generation (DFG) source by mixing ~ 1 W Ti:sapphire laser and 6 W Nd:YAG laser beams in a 50-mm MgO-doped long periodically poled lithium niobate (MgO:PPLN). The power of the DFG source is > 2 mW over the tuning range of 2.66-4.77 μm and its free-running linewidth is about 100 kHz. Combining various frequency stabilisation schemes for the Nd:YAG laser and the Ti:sapphire laser, the DFG frequency can be precisely controlled. Besides, its frequency can be determined better than 12 kHz by measuring the Ti:sapphire laser frequency using an optical frequency comb. Two high resolution spectroscopic studies on (12)C(16)O(2) molecule are demonstrated using this DFG source. The saturation spectra of R(18) and R(60) transitions of 00(0)1 ← 00(0)0 fundamental band at 4.2 μm and P(20) transition of [10(0)1, 02(0)1](I) ← 00(0)0 band at 2.7 μm have been observed and their absolute transition frequencies are measured with an accuracy better than 30 kHz.